D-(-)-Tartaric Acid #CAS147-71-7
CAS Number:147-71-7
Chemical Formula: C8H14Cl2N2
Synonyms:
tartaricacidd-minus
(2S,3S)-(-)-TARTARIC ACID FOR THE RESOLU
TARTARIC ACID, D-(-)-(P)
Appearance:White Crystals or Crystalline Powder
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
D-(-)-Tartaric Acid #CAS147-71-7
D-Tartaric acid, also known as (S, S)-tartrate or D-threaric acid, belongs to the class of organic compounds known as sugar acids and derivatives. Sugar acids and derivatives are compounds containing a saccharide unit which bears a carboxylic acid group. D-Tartaric acid has been detected but not quantified in loquats (Eriobotrya japonica). This could make D-tartaric acid a potential biomarker for consuming these foods. D-Tartaric acid is a secondary metabolite. Secondary metabolites are metabolically or physiologically non-essential metabolites that may serve as defense or signalling molecules. In some cases, they are molecules that arise from the incomplete metabolism of other secondary metabolites.
D-Tartaric acid is a white crystalline dicarboxylic acid found in many plants, particularly tamarinds and grapes. It is an acidulant that occurs naturally in grapes. It is hygroscopic and rapidly soluble, with a solubility of 150 g in 100 ml of distilled water at 25°c. It has a slightly tarter taste than citric acid, with a tartness equivalent of 0.8–0.9. It augments the flavor of fruits in which it is a natural constituent. It is used in grapeand limeflavored beverages and grape-flavored jellies. It is used as an acidulant in baking powder and as a synergist with antioxidants to prevent rancidity.
D-(-)-Tartaric acid is commonly used as a resolving agent in organic synthesis. It is the synthetic enantiomer of L-(+)-Tartaric acid and is utilized in the production of synthetic analgesics. Tartaric acid is the second largest alpha hydroxy acid (AHA) in terms of size, with glycolic acid being the smallest and citric acid being the largest. It serves as a precursor for the synthesis of ester derivatives such as D-tartaric acid diethyl ester, D-tartaric acid dimethyl ester, and D-tartaric acid diiso-propyl ester. Moreover, it is employed in the creation of chiral aziridine derivative, which is a common intermediate for manufacturing hydroxyethylamine class HIV protease inhibitors like saquinavir, amprenavir, and nelfinavir. In the food industry, it is extensively used as a beer foaming agent, for regulating food acidity, and as a flavoring agent. However, due to its challenging workability and potential skin irritation, it is not frequently utilized in cosmetic or anti-aging preparations.
Application of D-(-)-Tartaric Acid of:D-(-)-tartaric acid is widely used as an acidifier in beverages and food, similar to citric acid. It can also be used as a mordant for acid dye when combined with tannin. In the photographic industry, tartaric acid is used for some development and fixing processes. Its iron salts are photosensitive, making them suitable for blueprint production. Tartaric acid has the ability to form complexes with various metal ions, making it effective as a cleaning and polishing agent for metal surfaces. Potassium tartrate, known as Rochelle salt, is used to prepare Fehling reagent and is also employed as a laxative and diuretic in medicine. It is used as an intermediate for the synthesis of quinophan. Due to its piezoelectric properties, tartaric acid crystals find application in the electronics industry.
| D-(-)-Tartaric Acid Chemical Properties |
| Melting point | 172-174 °C(lit.) |
| alpha | -12.1 º (c=20, H2O) |
| Boiling point | 191.59°C (rough estimate) |
| density | 1,8 g/cm3 |
| refractive index | -12.5 ° (C=5, H2O) |
| Fp | 210 °C |
| storage temp. | Store below +30°C. |
| solubility | water: soluble100mg/mL, clear, colorless |
| form | Crystals or Crystalline Powder |
| pka | 3.0, 4.4(at 25℃) |
| color | White |
| Odor | odorless |
| Optical Rotation | [α]20/D 13.5±0.5°, c = 10% in H2O |
| Water Solubility | 1394 g/L (20 ºC) |
| Sensitive | Light Sensitive |
| Merck | 14,9068 |
| BRN | 1725145 |
| Dielectric constant | 35.9(-10℃) |
| Stability: | Stable. Incompatible with oxidizing agents, bases, reducing agents. Combustible. |
| Cosmetics Ingredients Functions | BUFFERING FRAGRANCE |
| InChI | 1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1 |
| InChIKey | FEWJPZIEWOKRBE-LWMBPPNESA-N |
| SMILES | O[C@@H]([C@H](O)C(O)=O)C(O)=O |
| LogP | -1.081 (est) |
| CAS DataBase Reference | 147-71-7(CAS DataBase Reference) |
| NIST Chemistry Reference | D-Tartaric acid(147-71-7) |
| EPA Substance Registry System | Butanedioic acid, 2,3-dihydroxy-, (2S,3S)- (147-71-7) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36/37-37/39-36 |
| WGK Germany | 3 |
| RTECS | WW7875000 |
| Autoignition Temperature | 425 °C |
| Hazard Note | Light Sensitive |
| TSCA | TSCA listed |
| HS Code | 29181200 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Dam. 1 |
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