Hypophosphorous acid #CAS6303-21-5
CAS Number:6303-21-5
Chemical Formula: HO2P
Synonyms:
HYPOPHOSPHOROUSACID,30%(W/V)SOLUTION
Hypophosphorus acid
Hypophosphorus acid, 50% w/w aq. soln.
Appearance:Colorless hygroscopic crystals or colorless oily liquid
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)
Hypophosphorous acid #CAS6303-21-5
It is deliquescent crystals or colorless oil. Melting point: 26.5℃. The relative density (specific gravity): 1.439 (solid, 19℃). It is soluble in water, ethanol and ether, and it can be mixed in any proportion with water, ethanol, acetone. In the air, it easily deliquesce to syrupy liquid, and the aqueous solution is acidic.
Hypophosphorous acid is monobasic acid, in aqueous solution, Hypophosphorous acid is strong acid, Ka = 10-2 (25℃); it is relatively stable at room temperature; disproportionation reaction can proceed at 130℃, decompose into phosphine and phosphorous acid:
2H3PO2=H3PO4+PH3
It has strong reduction, heavy metal salt solution can be restored to metals such as Cu2 +, Hg2 +, Ag +, such as:
4Ag+H3PO2+2H2)=4Ag+H3PO4+4H+
It is weak oxidizer, it can be reduced to phosphine, phosphine when encounters strong reducing agent.
It is non-combustible. But when contacts with the hole H agent, it will cause fire. When meets oxidizing agent, violent reaction and combustion can proceed. When it is heated to high, it can decompose into highly toxic phosphine gas, or even explode. It is corrosive. Hypophosphorous acid is often added into soft drinks, and because it is not absorbed. So the risk is small, but particularly strong hypophosphite hurt gastrointestinal. Accidentally it splashes into the eyes or contacts skin, plenty of water is used to washed. Production operators should wear protective clothing and other protective clothing. Production equipment should be sealed, workshop should be ventilated well.
Application Of Hypophosphorous acid
1. Hypophosphorous acid is used as reducing agent for electroless plating;
2. It can be used to prevent discoloration of phosphoric acid resin;
3. It is used as esterification catalyst, the refrigerant;
4. It is used to produce hypophosphite, sodium salts, manganese salts, iron salts are generally used as nourishing substances;
5. Hypophosphorous acid is used in medicine and as reducing agent, the determination of arsenic, tellurium and separation of tantalum, niobium and other reagents.
6. It is strong reducing agent, It can be used for the preparation of sodium hypophosphite, calcium phosphate and other hypophosphite.
7. It can be used for the plating bath. Pharmaceuticals. reducing agent. general reagents.
8. It is strong reducing agent, it can be used in making sodium hypophosphite, calcium phosphate and other hypophosphite.
9. This product is widely used as reducing agent, Ag, Cu, Ni, Hg and other metals are reduced to the corresponding metal, for the verification of As, Nb, Ta and other reagents, it can be used for the preparation of Na, K, Ca, Mn, Fe and other types of hypophosphite.
Hypophosphorous acid is primarily used for electroless nickel plating. It is involved in the reduction of arenediazonium salts. It acts as an additive in Fischer esterification reactions. Also, it serves as a neutralizing agent, antioxidant, catalyst in polymerization and poly condensation, and wetting agent. Further, it is used in the formulation of pharmaceuticals, discoloration of polymers, water treatment and retrieval of precious or non-ferrous metals. In addition to this, it is used as bleaching agents for plastics, synthetic fibers, decolorizing agent and for color stabilization during the manufacture of chemicals and several plastics.
| Hypophosphorous acid Chemical Properties |
| Melting point | -25 °C |
| Boiling point | 108 °C (759.8513 mmHg) |
| density | 1.206 g/mL at 20 °C(lit.) |
| vapor pressure | <17 mmHg ( 20 °C) |
| storage temp. | no restrictions. |
| solubility | very soluble in H2O, ethanol, ethyl ether |
| pka | pK1 1.1. |
| form | hygroscopic crystals or colorless oily liquid |
| color | Colorless |
| PH | pKa1= 1.00(25℃) |
| Water Solubility | SOLUBLE |
| Merck | 13,4894 |
| Stability: | Stable. Incompatible with strong bases. Reacts violently with oxidizing agents, strong bases, mercury (II) nitrate and mercury (II) oxide. Do not heat above 100 C. |
| InChI | 1S/H3O2P/c1-3-2/h3H2,(H,1,2) |
| InChIKey | GQZXNSPRSGFJLY-UHFFFAOYSA-N |
| SMILES | O[PH2]=O |
| CAS DataBase Reference | 6303-21-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Hypophosphorous acid(6303-21-5) |
| EPA Substance Registry System | Phosphinic acid (6303-21-5) |
| Safety Information |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3264 8/PG 3 |
| WGK Germany | 1 |
| RTECS | SZ6400000 |
| TSCA | TSCA listed |
| HazardClass | 8 |
| PackingGroup | II |
| HS Code | 28111990 |
| Storage Class | 8B - Non-combustible corrosive hazardous materials |
| Hazard Classifications | Eye Dam. 1 Met. Corr. 1 Skin Corr. 1B |
| Hazardous Substances Data | 6303-21-5(Hazardous Substances Data) |
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